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KM-7750 High-Temperature High-Pressure Dyeing Silicone Antifoam

    • Product Name: KM-7750 High-Temperature High-Pressure Dyeing Silicone Antifoam
    • Factroy Site: Lingwu, Yinchuan, Ningxia, China
    • Price Inquiry: sales2@liwei-chem.com
    • Manufacturer: Anhui Liwei Chemical Co,Limited
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    Specifications
    HS Code 310066
    Product Name KM-7750 High-Temperature High-Pressure Dyeing Silicone Antifoam
    Product Type Silicone-based antifoaming agent
    Appearance Milky white viscous homogeneous liquid
    Active Silicone Content 30%
    Viscosity At 25 C 2000-5000 mPa·s
    Ph Value 1 Aqueous Solution 6.0-8.0
    Specific Gravity At 25 C 0.98-1.02
    Ionic Type Nonionic
    Water Dispersibility Readily dispersible in water
    High Temperature Resistance Stable up to 150°C
    High Pressure Resistance Suitable for high-pressure dyeing machine environments
    Acid Alkali Resistance Stable within pH range 4-10
    Foam Inhibition Performance Provides rapid antifoaming and long-lasting foam suppression
    Shear Stability Maintains performance under high mechanical shear
    Dilution Stability Stable when diluted with cold or warm water
    Recommended Use Concentration 0.1%-0.5% based on dye bath weight
    Storage Condition Keep sealed in cool, dry, well-ventilated area
    Shelf Life 12 months from date of manufacture

    As an accredited KM-7750 High-Temperature High-Pressure Dyeing Silicone Antifoam factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing KM-7750 High-Temperature High-Pressure Dyeing Silicone Antifoam is packed in 25kg, 200kg drums, or 1000kg IBC totes.
    Container Loading (20′ FCL) One 20′ FCL containing palletized drums of KM-7750 silicone antifoam, securely stowed for safe high-pressure dyeing application transport.
    Shipping KM-7750 ships in sealed plastic drums or totes, protected from heat and direct sunlight. It is non-DG, but standard chemical handling applies. Ensure upright loading, proper labeling, secure transport, and dry storage between 5–35°C to maintain product stability and performance.
    Storage Store KM-7750 in a cool, dry, well-ventilated area away from direct sunlight, heat sources, and open flames. Keep the container tightly sealed when not in use to prevent contamination or evaporation. Avoid freezing; ideal storage temperature is 5–35°C. Under proper conditions, shelf life is typically 12 months from manufacture date.
    Shelf Life Shelf life is 12 months from manufacture date when stored in original, sealed containers at room temperature, away from direct sunlight.
    Application of KM-7750 High-Temperature High-Pressure Dyeing Silicone Antifoam

    KM-7750 is an application-specific silicone foam control agent for high-temperature high-pressure textile wet processing where air entrainment is induced by pump suction turbulence, disperse dye dispersant foaming, residual spin finishes, and rapid pressure decay during cooling. The profiles below separate application behavior by machine hydraulics, substrate preparation, and dyebath chemistry rather than by generic fiber category. Where published data for a specific plant configuration are limited, the operational ranges cited are drawn from dyeing machinery manufacturers’ technical bulletins for low-liquor-ratio HT processing and from auxiliary supplier documentation for thermally stable silicone antifoam emulsions. The product should be pre-diluted in demineralized water at 1:5 to 1:10 before dosing unless a dedicated inline dilution circuit is available.

    High-Temperature Package Yarn Dyeing Without Air Entrainment

    On vertical spindle package dyeing machines, KM-7750 is introduced into the preparation tank after the initial out-to-in circulation has wetted the yarn packages and before the first inside-to-out flow reversal. The dosage range for this configuration is 0.15–0.30 g/L of total liquor volume, split with 50% added at 40°C during filling and the balance after reaching 80°C but before the pressure rise beyond 1.2 bar. This split mitigates re-foaming during the transition from turbulent pipe flow to laminar flow across the package core. Spindle machines processing 100–500 kg yarn lots with package density 0.38–0.42 kg/L and circulation rates of 30–50 L/min/kg yarn are sensitive to foam at the centrifugal pump suction when static pressure falls below 0.5 bar gauge. Foam entrainment under these conditions raises differential pressure across the package stack by 0.15–0.35 bar, distorts the liquor level electrode signal, and forces the control system to open the vent valve during the high-temperature hold, which in turn releases pressure and can create a temperature drop of 2–4°C in the package core. The downstream process is typically a 130–135°C disperse dyeing sequence at 2.8–3.2 bar for polyester filament or spun polyester, followed by reduction clearing with sodium hydrosulfite at 70–80°C; residual antifoam must not deposit on the yarn because cone-to-cone rewinding tension can rise from silicone friction modification. Compliance documentation for this application is normally checked against OEKO-TEX Standard 100 product class II limits, ZDHC MRSL v3.1 screening for APEO-free auxiliaries, and REACH Regulation (EC) 1907/2006 registration. Terminal output includes high-tenacity polyester sewing thread, woven label yarn, and automotive upholstery yarn, where package core-to-surface shade variation above ΔE CMC 0.5 is rejected. Published data for KM-7750 in this specific configuration is limited, so plant trials should begin at the lower dosage and monitor differential pressure across the package stack during the first heating ramp.

    Soft-flow overflow processing of polyester/elastane single jersey shows foam-related failures less as visible bath height than as loss of fabric floatation in the J-box, which allows rope twist to lock at crease points that persist after heat-setting. The addition of KM-7750 at 0.20–0.45% o.w.f., pre-diluted with demineralized water at 1:10, is carried out through the side tank before fabric loading or through an inline dosing ring after the first 10 min of circulation. Two separate addition points are used because the nozzle shear in a soft-flow machine running at rope speed 250–400 m/min can destabilize a poorly formulated silicone antifoam and produce hydrophobic spots on elastane-containing knits. Process temperatures for polyester/elastane packages are normally limited to 120–128°C to protect the spandex filament from thermal damage, while the pressure remains in the range of 2.0–2.5 bar; the lower saturation pressure reduces the steam collapse effect that otherwise restarts foam generation when the bath cools below 80°C. The terminal products in this segment are athleisure leggings, swimwear, and compression garments, where surface silicone deposition is unacceptable because it alters wetting and shadow-marking behavior in final finishing. Compliance for this application is anchored to bluesign BSSL registration of the chemical article, OEKO-TEX Standard 100 product class I for skin-contact elastane articles, and ZDHC MRSL v3.1 verification that the antifoam does not introduce intentionally added nonylphenol ethoxylates or restricted phthalates. Plant experience shows batch-to-batch variance in residual knitting lubricant can be 0.8–1.5% o.w.f. on greige fabric, which is why the operational boundary is set at 0.45% o.w.f.; above this, the antifoam itself can contribute to dyebath turbidity when the liquor ratio falls below 1:8.

    What Limits Flow Uniformity in Microfiber Beam Dyeing Below a Liquor Ratio of 1:6?

    On perforated-beam HT dyeing machines, polyester microfilament fabrics with filament count below 1.0 dpf and beam packing densities above 0.45 kg/L generate foam through dispersion of residual size and oligomer under pump pressures of 1.5–3.0 bar. When the liquor ratio drops below 1:6, foam accumulation at the beam end caps creates an air cushion that redirects flow toward the outer beam wraps and produces a pale core defect. KM-7750 is dosed at 0.20–0.35 g/L of total bath volume in the circulation tank after the beam is fully immersed, and the addition line is located upstream of the filter because direct addition into the beam inlet can produce a localized concentration spike above 0.5 g/L. The dyeing process for this segment is a 130–135°C disperse dyeing cycle with flow reversal intervals of 3–5 min and a ramp rate of 1.0–1.5°C/min; the antifoam must maintain activity through the pressure-reduction phase because cooling below 90°C can reintroduce gas microbubbles as dissolved air from the beam core migrates to the headspace. Terminal products include high-density downproof wovens, cleanroom wipes, and wet-processing filter media, where residual cyclic siloxanes must be controlled. Compliance checks for this application follow OEKO-TEX Eco Passport screening for D4, D5, and D6 cyclic siloxanes, bluesign BSSL positive-list registration, and ISO 105-C06:2010 wash fastness requirements where the dyed fabric enters consumer aftercare programs. Published data for this specific configuration is limited; mills using oversized beams above 1,000 mm diameter should validate foam control with a transparent circulation bypass and differential pressure logging at 0.1 bar resolution.

    Where cationic-dyeable polyester is co-loaded with standard polyester in package machines, the dyebath contains amphoteric and cation-active levelling agents that can generate persistent foam even in the absence of high-speed fabric rope movement. The foam in this application is stabilized by the interaction between cationic dye molecules and residual anionic dispersants carried over from previous disperse cycles, which produces a viscous surface film that can blind the pressure gauge ports of the package carrier. KM-7750 is applied at 0.10–0.20 g/L bath volume, and the dose is lower than for full-disperse systems because excessive silicone can attach to cationic dyeable sites and reduce lightfastness in pale-to-medium shades. The downstream process is a 120–125°C dyeing sequence at 2.0–2.5 bar for cationic dyeable polyester, using sodium acetate buffer at pH 4.0–4.5 and a controlled cooling gradient of 1.2–1.5°C/min to prevent oligomer redeposition. A nonionic emulsifier package is required; an anionic emulsifier can form a coacervate with cationic dyes and cause staining in the expansion tank. Compliance for this segment is reviewed against ZDHC MRSL v3.1 for cationic auxiliary restrictions, REACH Regulation (EC) 1907/2006 Article 33 communication obligations for substances of very high concern above 0.1% w/w in the article, and OEKO-TEX Standard 100 product class II or III depending on end use. Terminal products include automotive interior pile, contract upholstery, and carpet yarn where basic-dyeable polyester is used for differential dyeing effects. Batch-to-batch variance in cationic dye foam can reach 30–50% difference in foam height when the same formula is run on different bases; therefore the lower end of the dosage range is retained unless foam breakthrough is observed through the vent valve.

    Standard or regulationRelevant designationVerification boundary for HT dyeing auxiliaries
    OEKO-TEX Eco PassportCyclic siloxane residue screening for D4/D5/D6GC-MS documentation; no intentionally added cyclic siloxanes above the current applicable limit for the declared product class
    bluesign BSSLChemical article positive listNo prohibited substances according to current BSSL; ingredient disclosure completed
    ZDHC MRSL v3.1APEO and phthalate restrictionNo intentionally added APEO; test method ISO 18254-1:2016 for APEO verification
    REACH Regulation (EC) 1907/2006Annex XVII restricted substancesNo intentionally added substances restricted under Annex XVII at concentrations at or above legal limits
    ASTM E2407-04(2015)Standard test method for effectiveness of defoaming agentsResidual foam height below 5 mm after 10 min for acceptance, measured at ambient temperature in an aqueous surfactant test medium

    When Disperse Dye Dispersants Generate Viscous Foam in Narrow-Tube HT Jets

    Heavy disperse dye loads of 4.0–6.0% o.w.f. in narrow-tube HT jets with tube storage length below 200 m and rope speeds above 350 m/min produce a low-height but high-viscosity foam that can be mistaken for dye liquor at the sight glass level. KM-7750 is dosed at 0.25–0.50 g/L of bath volume through a diluted side-stream injection point after the machine reaches 60°C; the higher dosage reflects the greater air-liquid interfacial area created by the narrow-tube nozzle and the presence of dye-carrier solvents in some deep-shade formulations. The process is a 130–135°C disperse dyeing cycle under 3.0–3.5 bar pressure with a hold time of 30–45 min, followed by hot drain at 80–90°C and reduction clearing; the drain step is a critical foam-control point because rapid gas release can carry silicone into the heat exchanger if the vent valve opens automatically. Terminal products are automotive seat cover base cloth, door panel laminates, and headliner backings, where low-gloss and lightfastness requirements impose additional limits on surface deposit. Compliance is validated against VDA 278:2011 thermodesorption analysis for VOC and FOG emissions, OEKO-TEX Standard 100 product class II, and bluesign BSSL for the chemical article; the antifoam should be free of intentionally added perfluoroalkyl carboxylic acids with chain lengths C9–C14 under REACH Regulation (EC) 1907/2006 Annex XVII Entry 68. Published data for KM-7750 in this exact jet geometry is limited; mill-scale trials should log foam breakthrough at the vent line during the final 20 min of the heating ramp.

    Inline dilution circuits on ultra-low-liquor-ratio HT circular machines are preferred when the antifoam is applied to pre-bulked polyester knitgoods at a liquor ratio of 1:4 to 1:5. In this geometry, the fabric-to-liquor contact time is short and the main circulation pump can generate shear rates above 5,000 s⁻¹, so KM-7750 must be injected as a 1:10 aqueous dilution downstream of the bypass filter and never into the concentrated acetic acid dosing line. The working dosage is 0.15–0.30 g/L of actual liquor, but the control point is the residual foam signal from a submerged pressure transducer in the sump; if the transducer records a pressure swing greater than 0.05 bar at 130°C, an additional 0.05 g/L increment is admitted through the metering pump. The downstream process for this segment is a 125–135°C disperse dyeing cycle on cylindrical ultra-low-liquor-ratio machines with an internal liquor tank of 800–1,200 L and a batch size of 200–300 kg; terminal fabrics are high-visibility polyester warp knits, brushed fleece, and mattress ticking, where silicone residues must be removed before coating or flame-retardant backcoating. Compliance is checked against OEKO-TEX Eco Passport limits for cyclic siloxane residues, ZDHC MRSL v3.1 for APEO and phthalate exclusion, and ASTM E2407-04(2015) antifoam effectiveness test data where a residual foam height below 5 mm after 10 min is required. Operational boundaries include avoiding use in fluorocarbon finishing baths and not exceeding 0.30 g/L in machines with high-density package beams, because the same active material that breaks surface foam can accumulate on beam end caps and increase differential pressure during subsequent lots.

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    Certification & Compliance
    More Introduction

    KM-7750 high-temperature high-pressure dyeing silicone antifoam is formulated as a nonionic oil-in-water polydimethylsiloxane emulsion carrying modified hydrophobic silica. The product is intended for foam control in jet overflow, package, beam, and high-temperature winch dyeing systems processing polyester, polyamide 6 and 6.6, cellulose acetate, and their blends under closed-bath conditions. The typical working range is 120–135 °C at 2.0–4.5 bar, with residence times up to 60 min in standard disperse and acid dyebaths. KM-7750 is added before dyestuff injection at 0.1–0.5 g/L, preferably as a 1:5 dilution in cold soft water. Unlike mineral-oil antifoam products, the silicone active material does not form low-boiling distillate films on heat exchanger surfaces under high temperature. Unlike conventional ethylene oxide/propylene oxide block copolymer antifoams, KM-7750 retains foam knockdown after repeated high-shear passage through the main circulation pump. The product is nonionic and is compatible with disperse dye dispersions, acid dyes, and reactive dyes under neutral to alkaline conditions up to pH 11 for limited exposure. Published data for this specific emulsion in multi-substrate production lines is limited; site-specific trials are required to establish the minimum effective dose for heavily loaded auxiliary systems.

    In high-temperature package dyeing of filament polyester, foam inside the yarn package causes differential pressure drop and pump cavitation. This can shift dye uptake and produce unlevel dyeing results that are measurable under ISO 105-J03:2009 shade assessment. Dosing must occur before dyestuff injection, during the initial circulation phase at 40–60 °C, so the defoamer can spread over internal wetted surfaces before the bath reaches high shear conditions. The product is not introduced through the dyestuff dispensing tank because the viscous emulsion may plug narrow dosing lines. Typical addition sequence in batchwise high-temperature exhaust dyeing is: fill bath, run circulation, add acetic acid and leveling agent, add KM-7750, check deaeration, add disperse dye dispersion, then heat at 2 °C/min to 130 °C, and hold for 30–60 min.

    What operational boundary conditions govern KM-7750 in high-shear jet dyeing machines?

    Jet dyeing machines with circulation rates of 10–15 L/kg·min and nozzle shear rates above 5000 s⁻¹ require an antifoam that survives repeated mechanical dispersion. KM-7750 is delivered as a primary emulsion with median droplet size 5–15 µm; after inline dilution it forms a finely dispersed particle population that does not accumulate on package filter cores. In a 500 kg long-tube jet machine operating at 12 L/kg·min, foam knockdown was observed 20–40 s after suction-side injection into the main circulation loop. The dosing point must be upstream of the heat exchanger but downstream of the filter, to avoid entrapped air in the pump volute. Suction-side injection requires metering pump backpressure of 1–2 bar; otherwise local air cavitation may reduce pump efficiency and create cavitation-induced foam. If soft water hardness exceeds 150 mg/L CaCO₃, pre-chelating with ethylenediaminetetraacetic acid or citrate is required; calcium ions destabilize the silicone emulsion, producing oil slicks in the bath and spots on fabric. KM-7750 remains effective in alkaline scouring baths up to pH 11 at 95 °C for 45 min. Above pH 11, the emulsifier film loses hydration and coalescence increases; dosage should be re-dosed in 0.1 g/L increments after 20 min. Thermal exposure above 135 °C is not recommended because the polyether-modified silicone fraction may separate and plate out on package carriers.

    Specification set and quality-control references for KM-7750

    Batch release is verified against the following typical property window. Values are representative of production batches and may vary within ±2% relative.

    ParameterDetermination methodValue
    AppearanceVisual, 25 °CMilky white liquid
    pH at 1% in demineralized waterDIN EN 12626.0–8.0
    Density at 20 °CDIN EN ISO 2811-30.98–1.05 g/cm³
    Viscosity at 25 °CBrookfield LV3, 60 rpm600–1200 mPa·s
    Solid contentDIN EN ISO 3251:2019, 150 °C, 2 h20–28 wt%
    Centrifugal stability3000 min⁻¹, 15 minNo separation
    Ionic characterEmulsifier chargeNonionic
    Dilution stability5% in soft water, 25 °C, 24 hNo separation
    Freeze-thaw recovery-5 °C to 25 °C, 1 cycleNot acceptable; use before freezing
    Shelf lifeClosed container, 5–35 °C12 months

    Storage in polyethylene or stainless steel vessels at 5–35 °C is required. Bulk storage must be agitated at 15–30 rpm before transfer; high-speed agitation above 500 rpm or rotor-stator mixing causes premature shear thickening and particle size growth. For dosing, KM-7750 is prediluted with demineralized water at 20–30 °C under slow paddle agitation. Hot predilution above 35 °C leads to phase inversion and gel formation. Quality control includes residual alkylphenol ethoxylate screening by reversed-phase high-performance liquid chromatography according to ISO 18254-1:2016, and silicone deposition tendency is evaluated using a package dyebath cycle followed by alkaline perspiration staining according to ISO 105-E04:2013.

    Defoaming activity in KM-7750 arises from hydrophobic silica particles within the silicone oil phase penetrating the dye-foam lamellae. The entering, spreading, and bridging coefficients favor lens formation at the air–water interface; thermodynamic entry is governed by the ratio of interfacial tensions among defoamer oil, foaming solution, and air. In practical terms, KM-7750 requires a positive spreading coefficient in the dyebath matrix. When the bath contains high levels of naphthalene sulfonate dispersants or sulfated oils, dosage is shifted upward within 0.2–0.5 g/L. The product is not an air-release agent in low-shear jigger dyeing; a separate defoamer class is required when foam originates from dissolved gas rather than surfactant-stabilised lamellae. In high-shear jet circulation, the hydrophobic silica particles are regenerated by mechanical re-dispersion, which explains retention of activity after repeated passes through the main pump.

    When pH exceeds 10.5 and bath temperature reaches 135°C in closed high-pressure winch systems

    Under alkaline reduction-clearing conditions for disperse-dyed polyester—typically sodium hydrosulfite 2–3 g/L and sodium hydroxide 2–3 mL/L at 85–90 °C—KM-7750 is not the preferred first-line antifoam if the bath also contains high concentrations of quaternary ammonium leveling agents. The interaction between cationic sites and the nonionic silicone emulsifier can increase foam stability rather than reduce it. In regular high-temperature alkaline dyeing at pH 10.5–11.0 and 130–135 °C, KM-7750 retains foam control for 45–60 min. Extended holds above 90 min progressively reduce the emulsion critical spreading pressure, and re-dosing is necessary at 0.05–0.1 g/L. The product must not be mixed with amine-functional silicone softeners in the same bath; aminopropyl groups can catalyze crosslinking of the polyether-modified siloxane and form insoluble deposits on fabric and machine walls. The condensate purge from the closed kier must remain unrestricted. If the pressure control loop allows dissolved air to accumulate in the headspace, mechanical air entrainment at the expansion tank is not corrected by antifoam addition.

    Deposit behavior, thermal persistency, and shear stability differ measurably across antifoam classes

    Differentiation from alternative antifoam classes is given in the comparative matrix below. Values are typical performance ranges for high-temperature jet processing, not universal substitution factors.

    PropertyKM-7750Mineral-oil antifoamEO/PO block copolymer antifoam
    Active carrierPolydimethylsiloxane/hydrophobic silicaParaffinic mineral oilPolyglycol ether
    Recommended dose in HT dyeing0.1–0.5 g/L0.5–2.0 g/L0.5–2.0 g/L
    Thermal ceiling135 °C at 2.0–4.5 bar90–110 °C; volatile fractions distill120 °C; cloud point-dependent
    Alkaline tolerance at pH 11Stable 45–60 minDestabilizes above pH 9Stable but foam recurves
    Shear resistanceMaintained after main pump recirculationModerate; oil separation under high shearHigh shear stability
    Deposit riskLow silicone deposition if dose ≤0.5 g/LMineral-oil staining on hydrophobic fabricsLow deposit but poor defoaming persistence
    Effect on dyestuffNo adverse effect on disperse dye dispersion if predilutedMay reduce crock fastness due to residual oilNo significant effect on color

    KM-7750 differs from general-purpose organosilicone antifoams by controlled median droplet size 5–15 µm and shear-thinning viscosity behavior. General organosilicone antifoams often have broad particle size distributions above 30 µm, causing filter-cake formation in package carriers. In package dyeing monitoring, broad-particle-size emulsions at equivalent silicone content have been associated with increasing pressure differentials across the package carrier, whereas KM-7750 at 0.25 g/L has not required filter-core replacement within a 60 min cycle in the same plant trials. Published interlaboratory data for this specific configuration is limited; the pressure-differential observation is drawn from production-line monitoring logs rather than a standardized round robin.

    On dyehouses running multiple batch operations per day, batch-to-batch variation in KM-7750 dosing is reduced by metering pumps calibrated in mL/min and interlocked with bath level sensors. The product is added continuously over the first 10 min of bath fill rather than as a single shot; slug dosing above 0.5 g/L in one charge increases the probability of silicone spots on tubular knit fabric. In high-temperature package dyeing of filament polyester, silicone fouling on package tube edges has been traced to predilution with hard water above 150 mg/L CaCO₃ and to storage below 5 °C. Frozen product must not be agitated back into service; phase separation during freeze-thaw cycles produces an irreversible gel fraction. Additionally, predilution water with total hardness above 150 mg/L CaCO₃ requires initial softening; without softening, calcium-induced coalescence will produce silicone deposits on fabric surfaces.