| HS Code | 509338 |
| Product Name | KM-73A Food-Grade Silicone Antifoam Emulsion |
| Appearance | milky white uniform emulsion |
| Active Silicone Content | 30% by weight |
| Viscosity | 1000 mPa·s at 25°C |
| Specific Gravity | 1.00 at 25°C |
| Ph | 7.0 |
| Emulsion Type | oil-in-water nonionic emulsion |
| Odor | nearly odorless |
| Dilution Stability | readily dilutable with water |
| Foam Inhibition Property | rapid foam suppression with long-lasting defoaming action |
| Temperature Resistance | effective and stable up to 120°C |
| Food Grade Standard | compliant with food-contact silicone antifoam regulations |
| Storage Temperature | 5°C to 35°C |
| Shelf Life | 12 months from production date in unopened container |
As an accredited KM-73A Food-Grade Silicone Antifoam Emulsion factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | KM-73A Food-Grade Silicone Antifoam Emulsion is packaged in sealed 25 kg polyethylene-lined pails, ensuring safe handling, stability, and contamination-free storage. |
| Container Loading (20′ FCL) | 20′ FCL loading of KM-73A food-grade silicone antifoam emulsion: packed in sealed drums/IBCs, secured on pallets, container clean, dry, and contamination-free. |
| Shipping | KM-73A ships in sealed drums or totes via ground freight. Protect from extreme heat and freezing; store between 5–35°C. Non-hazardous for routine transport when packaged properly. Ensure containers remain upright and secured to prevent leakage. Standard delivery takes 3–7 business days depending on destination. |
| Storage | Store KM-73A Food-Grade Silicone Antifoam Emulsion in its original, tightly sealed container in a cool, dry, well-ventilated area away from direct sunlight, heat sources, and freezing temperatures. Ideal storage range is 5–30°C. Avoid contamination by keeping the container clean and dry. Under proper conditions, shelf life is typically 12 months from manufacture date. |
| Shelf Life | Shelf life is typically 12 months from manufacture when stored sealed in original container at recommended temperatures. |
KM-73A Food-Grade Silicone Antifoam Emulsion is metered into beet sugar extraction lines where raw juice produces persistent foam from saponins, pectin fragments, and denatured beet proteins released during countercurrent diffusion. The emulsion is fed after cold liming and before the first-effect evaporator feed tank. Addition rates of 2 ppm to 10 ppm active polydimethylsiloxane relative to raw juice mass are typical for diffuser overheads and evaporator feed streams. Injection uses a diaphragm dosing pump with discharge pressure of 0.5 bar to 2.0 bar. The diluted emulsion remains effective in raw juice at pH 5.5 to 7.0 and at feed temperatures up to 85 °C. The presence of suspended solids does not require pre-filtration. Foam carryover from the vapour separator is reduced. Heat-transfer surfaces in mechanical vapour recompression falling-film evaporators remain cleaner between cleaning cycles. Foam reduction is verified during dosing trials by the Ross-Miles method according to ASTM D1173. Compliance is referenced to FDA 21 CFR 173.340 and EU Regulation (EC) No 1333/2008 Annex II for E900. Finished streams are white beet sugar, molasses, and pelletized beet pulp. The emulsion should not be dosed upstream of carbonatation when excess nonionic emulsifier loading could increase filter pressure drop. Published data for KM-73A in diffuser-specific dosing locations is limited; therefore, the injection point is validated by foam height sampling rather than assumed from generic sugar mill data.
Submerged aerobic fermentation of Aspergillus niger for citric acid monohydrate generates voluminous foam from extracellular polysaccharides, mycelial fragments, and pH-dependent protein denaturation. In a 10 m³ working-volume stirred-tank bioreactor fitted with two Rushton impellers and an air sparge rate of 1.0 vvm, foam rises into the headspace and can blind exhaust filters. KM-73A is added as a sterilized aqueous dilution at 1:10 with deionized water. Terminal sterilization is carried out at 121 °C for 15 min in a stainless-steel pressure vessel. Post-autoclave creaming index is measured; values above 5% by volume indicate unsuitable heat stability for that batch. Initial charge rates range from 30 ppm to 80 ppm active polydimethylsiloxane based on initial working volume. Foam capacitance sensors trigger pulse additions of 5 ppm to 20 ppm active when the headspace foam interface exceeds the control setpoint. Over-addition above 120 ppm active may reduce the volumetric oxygen transfer coefficient kLa by blocking the gas-liquid interface, especially at low impeller power input of 1.5 kW m⁻³. The emulsion is introduced upstream of the air sparger, not into the impeller vortex, to minimize shear-induced droplet size reduction below 10 µm. Droplets below 10 µm can remain dispersed and reduce oxygen transfer rather than spread at the foam lamella. Published data for KM-73A in this specific configuration is limited; therefore, on-site validation against dissolved oxygen probes is required. Compliance for food enzymes and citric acid is governed by FDA 21 CFR 173.340 and EU Regulation (EC) No 1333/2008 Annex II for E900. Finished products are citric acid monohydrate crystals, fungal alpha-amylase, and yeast extract powder. Recovery operations include vacuum filtration and rotary drum filters. Residual silicone in the spent mycelium filter cake can alter ring dryer drying kinetics. A daily CIP cycle with 1% to 2% NaOH at 75 °C removes silicone films from stainless internals. The use of KM-73A does not replace mechanical foam breakers in high-viscosity broths above 800 mPa·s. At pH below 2.0 during citric acid production, the emulsion may show reduced stability; inline dilution with acidified water is avoided in favour of neutral water. Lot-specific Kosher and Halal certification should be verified before use in enzyme products destined for dietary markets.
| Process stream | Regulatory reference | Control / analytical method |
|---|---|---|
| Beet sugar juice | FDA 21 CFR 173.340; EU Regulation (EC) No 1333/2008 Annex II E900 | Foam height by ASTM D1173 |
| Fermentation broth | FDA 21 CFR 173.340; EU Regulation (EC) No 1333/2008 Annex II E900 | Dissolved oxygen, kLa, post-autoclave creaming index |
| Whey concentrate | FDA 21 CFR 173.340; EU Regulation (EC) No 1333/2008 Annex II E900 | Vapour separator differential pressure; silicon in powder by ISO 11885 |
| Flume water | FDA 21 CFR 173.340 | Turbidity, optical sorter performance, silicon on produce by ISO 11885 |
| Frying oil | FDA 21 CFR 173.340 | Silicone in oil by ISO 11885; fryer hood oil mist |
| Liquid egg | FDA 21 CFR 173.340; EU Regulation (EC) No 1333/2008 Annex II E900 | Silicon in powder by ISO 11885 |
Demineralized sweet whey entering a four-effect falling-film evaporator produces foam when the protein content exceeds 12 wt% and the feed temperature reaches 60 °C during preheating. KM-73A is metered into the balance tank at 10 ppm to 30 ppm active silicone relative to feed stream mass. The metering point is after the plate heat exchanger and before the distribution head of the first effect. Continuous dosing is preferred over slug addition because foam collapse in high-viscosity WPC retentate is slower than in raw juice. The diluted emulsion is prepared at 1:20 using 45 °C potable water and held with slow agitation at less than 60 rpm. Excessive agitation accelerates coalescence. Foam-control performance is monitored by differential pressure across the vapour separator; an increase above 8 kPa indicates breakthrough. Proteinaceous foam carryover into the MVR compressor reduces impeller balance and accelerates deposition on vanes. KM-73A addition at the specified range does not alter protein denaturation index or bulk density of spray-dried WPC80, as measured by differential scanning calorimetry denaturation enthalpy and loose bulk density. Compliance references include FDA 21 CFR 173.340 and EU Regulation (EC) No 1333/2008 Annex II for E900. Residual silicone in the final powder is controlled by addition rate and evaporator residence time. Alkaline CIP with 1.5% NaOH at 80 °C is required to remove silicone-protein films from heating surfaces. The emulsion is not appropriate for use in infant formula streams unless a specific regulatory filing confirms the exact residual level. Finished products are WPC80, whey permeate powder, and lactose monohydrate.
Cut leafy greens and carrot sticks handled in recirculating flume water release fine plant cell debris, soluble proteins, and natural saponins that generate stable foam during air-knife dewatering and optical sorting. KM-73A is injected into the flume balance tank at 2 ppm to 5 ppm active silicone relative to water volume. Injection uses a peristaltic metering pump with continuous feedback from a turbidity sensor. Foam control prevents pump cavitation in the main circulation loop and improves the resolution of optical defect detection cameras. A post-rinse stage with 1% to 2% citric acid solution at 4 °C lowers pH and removes surface residues. The dilution water must be potable and free of residual chlorine above 4 ppm because chlorine can destabilize the nonionic emulsion. Residual silicone carryover on the final product falls under FDA 21 CFR 173.340 and requires verification by laboratory extraction and silicon determination by ISO 11885. In flume water, the emulsion is effective at pH 5.5 to 8.0. Operations at pH below 5.0 using peracetic acid sanitizer may form oil-like coalescence on the water surface; the emulsion should be pre-diluted 1:100 before injection under these conditions. Finished products are ready-to-eat salad mixes, frozen cut leafy greens, and fresh-cut carrot coins.
KM-73A is water-dilutable and must never be introduced directly into hot fryer oil. Direct injection into oil at 175 °C causes instantaneous water flash and possible operator exposure. The emulsion is first mixed into a sidestream of cooled oil at 50 °C to 60 °C at a ratio of 1:10 and then returned to the fryer oil supply tank. Active silicone addition rates of 1 ppm to 5 ppm based on oil mass are typical in continuous potato chip fryers. Silicone addition at this level suppresses starch-protein foam at the oil surface and reduces oil mist above the fryer hood. Over-addition above 10 ppm active is not recommended because residual polydimethylsiloxane may appear in heat exchanger fouling deposits and oil smoke point may shift. The frying system includes a continuous filter and heat exchanger; KM-73A passes through the filter without adsorption on sheet filter media. Compliance with FDA 21 CFR 173.340 applies to dimethylpolysiloxane as a defoaming agent in frying oil. Finished products are potato chips, corn-based snacks, and batter-coated extruded snacks. Oil turnover rates and fried food silica residues should be monitored when multiple antifoam sources are present.
Whole egg and egg yolk streams pumped through plate heat exchangers at 65 °C to 70 °C develop heat-stable foam due to lipoprotein denaturation and air incorporation from diaphragm pumps. KM-73A is dosed at 5 ppm to 15 ppm active silicone relative to liquid egg mass in the holding tank after pasteurization and before high-pressure spray dryer feed. The emulsion is diluted 1:50 in 15 °C potable water prior to injection. Addition reduces foam in the spray dryer feed line and prevents filter blockage in the atomizer nozzle circuit. It is not dosed into separated egg white streams where foaming performance for bakery use is critical. Compliance with FDA 21 CFR 173.340 is applicable; EU import requires E900 listing under EU Regulation (EC) No 1333/2008 Annex II. Silicone residue in egg powder is monitored by silicon content using ISO 11885. The emulsion should not be combined with alkaline phosphate buffer at pH above 9.0 because emulsion instability may produce oil separation. Finished products are whole egg powder, egg yolk powder, and frozen liquid egg for bakery supply chains.
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KM-73A is a food-grade silicone antifoam emulsion formulated as an oil-in-water dispersion of 30% active polydimethylsiloxane, with a nonionic emulsifier package and water as the continuous phase. The product appears as a milky white liquid with a density of 0.98–1.02 g/cm³ at 25 °C. Representative release data place the active silicone content at 29.5–31.5 wt%, Brookfield LVT viscosity at 200–600 mPa·s using spindle 2 at 60 rpm and 25 °C, and pH at 6.5–8.5 in 1% aqueous dilution. The emulsion particle size is specified as D50 5–25 µm and D90 ≤ 50 µm according to ISO 13320:2020 laser diffraction. This particle-size window is intended to balance rapid foam knockdown with sustained defoaming in aqueous food-processing fluids.
For direct food-contact use, the active dimethylpolysiloxane falls under FDA 21 CFR 173.340 as a defoaming agent in food, with residual silicone in food limited to 10 mg/kg unless otherwise specified in the applicable subparagraph. In the European Union, dimethylpolysiloxane is covered as food additive E900 under Regulation (EC) No 1333/2008; KM-73A is not itself a direct food additive and should be evaluated for carry-over in each finished food category. Unlike industrial silicone emulsions, the food-grade formulation does not rely on preservatives such as methylchloroisothiazolinone or formaldehyde donors, which can inhibit starter cultures or yeast viability in fermentation.
Compared with mineral oil or polyalkylene glycol defoamers, KM-73A does not depend on water solubility or temperature-dependent precipitation for activity. The polydimethylsiloxane phase has a surface tension of approximately 20–21 mN/m, below the surface tension of most aqueous food media, allowing dispersed droplets to spread on foam lamellae and rupture the film. This mechanism supports typical dosing in aqueous fermentation of 5–100 mg/kg active silicone, whereas mineral oil defoamers may require 100–1,000 mg/kg and can contribute extractable hydrocarbon residues. KM-73A is also distinct from 100% active silicone compound antifoams because it is water-dilutable in cold water at 1:10 to 1:100 without pre-emulsification in hot water or high-shear mixing.
The primary differences are chemical origin, residue profile, and foam-film interaction. Mineral oil defoamers contain a complex mixture of saturated hydrocarbons and may introduce extractable residues that are undesirable in high-moisture food matrices. Polyalkylene glycols can be water-soluble and may lose defoaming activity above their cloud point or interact with natural polymers. KM-73A is an emulsion of polydimethylsiloxane, and its foam-control function is based on a spreading mechanism rather than thermal precipitation. In agitated fermenters with air sparge rates of 0.5–1.5 vvm, the product is normally metered at 5–100 mg/kg active silicone, while mineral oil products may require approximately one order of magnitude higher dose to achieve equivalent foam height reduction.
| Parameter | KM-73A food-grade silicone emulsion | Mineral oil defoamer | Polyalkylene glycol defoamer |
|---|---|---|---|
| Active chemistry | Polydimethylsiloxane, 30% oil-in-water emulsion | Mineral oil with hydrophobic particles | Polyalkylene glycol or ester |
| Surface tension of active phase | 20–21 mN/m | 30–35 mN/m | 35–40 mN/m |
| Typical dose in aqueous food processing | 5–100 mg/kg active silicone | 100–1,000 mg/kg | 100–1,000 mg/kg |
| Water dispersibility | Cold-water dilutable, no high shear required | Requires emulsification or surfactant package | Water-soluble to water-dispersible depending on cloud point |
| Food-contact clearance | 21 CFR 173.340, E900 under EC 1333/2008 | Varies; many grades are not cleared for direct food use | Varies by polymer grade and regulatory region |
| Main limitation | Emulsion instability under freeze-thaw or excessive shear beyond recommended limits | Potential extractable hydrocarbon residue; lower efficiency on protein foam | Cloud-point sensitivity; possible pro-foaming at overdosing in some systems |
Foam film rupture with KM-73A occurs when dispersed polydimethylsiloxane droplets enter the foam lamella and spread at the air/water interface. The spreading coefficient is positive when the surface tension of the antifoam phase is lower than that of the foaming liquid. Because the product is an emulsion, droplet size distribution becomes the controlling variable for knockdown speed and persistence. In high-shear blending, coarse droplets above 50 µm may provide rapid knockdown but short persistence, while fine droplets below 5 µm may not enter the foam film rapidly. The specified D50 of 5–25 µm is therefore aligned with both knockdown and persistence in agitated vessels and continuous flow systems.
The material is standardised at a solids range of 30.0 ±1.5% because lower active content can reduce cost-in-use and higher active content may increase creaming tendency in low-shear storage. The emulsion remains pourable under recommended storage at 5–40 °C. Freeze-thaw cycling below 0 °C can separate the silicone phase from water; if freezing occurs, the product should not be returned to service without passing a homogeneity check by visual inspection and viscosity measurement. Storage above 45 °C accelerates emulsifier desorption and may increase particle coalescence. Shelf life in unopened original containers is 12 months from the date of manufacture. Diluted batches should be used within 24 hours unless a validated biocide is added, because the emulsion is water-based and preservative-free.
KM-73A should not be mixed with strong oxidizers, polyvalent metal salts, or quaternary ammonium-based biocides without compatibility testing, as destabilization of the emulsion may occur. The product should not be stored in iron or copper containers; high-density polyethylene or lined carbon steel is recommended for bulk storage. During clean-in-place operations, residual antifoam films on stainless steel surfaces can be removed with hot alkaline detergent followed by an acid rinse.
In closed fermenters, antifoam strategy is often coupled to dissolved oxygen control. Overdosing a silicone emulsion can reduce the volumetric oxygen transfer coefficient by coating gas-liquid interfaces, so the minimum effective dose must be determined using the production vessel’s gassing-out method. In a 10,000 L stirred-tank fermenter with 180 rpm agitation and air sparging, intermittent dosing of KM-73A diluted 1:10 in cold water is preferred to continuous overdose. Foam-level sensors at the vessel headspace and a diaphragm metering pump with 0.5–5 L/h capacity are typical field components. The diluted emulsion should be added to the rising foam rather than directly to the liquid surface to avoid rapid surfactant depletion.
In spray dryer feed tanks, KM-73A can be added to the concentrate before atomization. The product must not be subjected to recirculation through a positive displacement homogenizer at pressure above 200 bar because excessive shear can break the emulsion and reduce defoaming efficiency. In a two-fluid nozzle atomizer with air-to-liquid ratio 0.5:1 to 1.5:1, the silicone emulsion may reduce foam in the feed tank but has limited post-drying effect on powder properties. Published data for this specific configuration is limited, so pilot-scale verification is recommended before full production changes.
When KM-73A is incorporated into a food-contact coating or packaging-related formulation, the relevant end-use clearance may include 21 CFR 175.300 for resinous and polymeric coatings or 21 CFR 176.200 and 21 CFR 176.210 for defoaming agents in paper and paperboard. Silicone migration into aqueous food simulants should be measured under 21 CFR 175.300 or EU 10/2011 migration protocols. The migration rate is controlled by silicone concentration, coating thickness, and food-contact temperature; published data for this specific formulation is limited, so pilot-scale migration testing is required for packaging applications. In direct aqueous food processing, residual silicone is commonly verified by atomic absorption or inductively coupled plasma optical emission spectroscopy after sample digestion, with a reporting limit of 1 mg/kg silicon.